Issue 6, 1986
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Solid-state photochemistry of nitro compounds: structure–reactivity correlations

Kaillathe Padmanabhan,   Dietrich Döpp,   Kailasam Venkatesan  and  Vaidyanathan Ramamurthy  

Abstract

The molecular structures of 1-t-butyl-3,5-dimethyl-2,4,6-trinitrobenzene, 1-t-butyl-3,4,5-trimethyl-2,6-dinitrobenzene, and 1-t-butyl-4-acetyl-3,5-dimethyl-2,6-dinitrobenzene have been determined by single-crystal X-ray analyses with a view to establishing a structure-reactivity relationship in the photochemical intramolecular hydrogen-abstraction process in the solid state. The reactivity of these aromatic nitro compounds in the solid state has been rationalized in terms of relevant intramolecular geometrical parameters as well as intermolecular packing considerations.

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Article information

DOI
https://doi.org/10.1039/P29860000897
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1986, 897-906

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Solid-state photochemistry of nitro compounds: structure–reactivity correlations

K. Padmanabhan, D. Döpp, K. Venkatesan and V. Ramamurthy, J. Chem. Soc., Perkin Trans. 2, 1986, 897 DOI: 10.1039/P29860000897

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