The Molecular World

Chemical Kinetics and Mechanism

DOI: 10.1039/9781847557803
M Mortimer (Editor), P G Taylor (Editor)
ISBN (online): 978-1-84755-780-3
ISBN (print): 978-0-85404-670-6
Copyright: 2002

Table of Contents

Title	Page
Front cover DOI: 10.1039/9781847557803-FX001 (17Mb)		Full Access
Front matter DOI: 10.1039/9781847557803-FP001 (901Kb)		Full Access
The molecular world DOI: 10.1039/9781847557803-00001 (993Kb)	1	Full Access
Contents		License Access
Chemical kinetics	9	License Access
Introduction	11	License Access
A closer look at chemical reactions	18	License Access
Rate in chemical kinetics	24	License Access
Factors determining the rate of a chemical reaction	35	License Access
Determining experimental rate equations at a fixed temperature	42	License Access
The effect of temperature on the rate of a chemical reaction	65	License Access
Elementary Reactions	80	License Access
Reaction mechanism	92	License Access
Summary of part 1	104	License Access
Learning outcomes for part 1	105	License Access
Questions: Answers and comments	108	License Access
Exercises: Answers and comments	120	License Access
Further reading	131	License Access
Acknowledgements	132	License Access
The mechanism of substitution	133	License Access
Organic reactions	135	License Access
Reaction mechanisms	139	License Access
Ionic substitution reactions	150	License Access
SN2 and SN1 reaction mechanisms	166	License Access
SN2 versus SN1	175	License Access
Concluding remarks	179	License Access
Learning outcomes for part 2	180	License Access
Questions: Answers and comments	182	License Access
Acknowledgements	185	License Access
Elimination: Pathways and products	187	License Access
Introduction: ß-elimination reactions	189	License Access
The E2 mechanism	194	License Access
The E1 mechanism	203	License Access
Elimination versus substitution	208	License Access
Other useful elimination reactions	212	License Access
Learning outcomes for part 3	215	License Access
Questions: Answers and comments	216	License Access
Case study shape-selective catalysis using zeolites	225	License Access
Introduction	227	License Access
Structure, properties and classification of zeolites	230	License Access
Shape selectivity	242	License Access
Applications of shape selectivity	246	License Access
Zeolites as enzyme mimics	250	License Access
Mesoporous aluminosilicate structures	251	License Access
Conclusion	255	License Access
Acknowledgements	256	License Access
Index	257	License Access
CD-ROM information	262	License Access
Back cover DOI: 10.1039/9781847557803-BX003 (16Mb)		Full Access