Journal of the Chemical Society, Chemical Communications
Journal of the Chemical Society, Chemical Communications was published between 1972 - 1995.
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Paper
J. Chem. Soc., Chem. Commun., 1994, 2011 - 2012, DOI: 10.1039/C39940002011
Surface-mediated organometallic synthesis of [
SiO]–[RhH2(PMe3)4]+: the first example of a cationic organometallic complex attached to the silica surface by ion pairingSusannah L. Scott, Pascal Dufour, Catherine C. Santini and Jean-Marie Basset
The reaction of silica-supported bis(allyl)rhodium, (
SiO)(SiOX(Rh(
3-C3H5)21(X = H, Si) with PMe3 followed by H2 yields [RhH2(PMe3)4]+, 2, which is characterised by IR, solid-state 31P NMR and elemental analyses and extracted quantitatively from the surface by ion-exchange with Bun4NCl in nitromethane; the counterion of 2 is presumed to be a siloxy group [SiO]– of the silica surface.
