Issue 7, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Elucidation of the reversible carbon monoxide reactions of a paramagnetic rhodium(II) complex

Kim R. Dunbar,   Steven C. Haefner  and  Paul N. Swepston  

Abstract

Coordination of carbon monoxide to the rhodium(II) ether–phosphine complex [Rh(tmpp)2][BF4]21[tmpp = tris(2,4,6-trimethoxyphenyl)phosphine] initiates a redox reaction to produce the rhodium(III) complex [Rh(tmpp)2][BF4]32 and the dicarbonyl rhodium(I) species [Rh(tmpp)2(CO)2][BF4]3; the latter readily loses a CO ligand to form [Rh(tmpp)2(CO)][BF4]4 which enters into a second redox reaction with 4 to regenerate the original rhodium(II) radical 1.

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Article information

DOI
https://doi.org/10.1039/C39910000460
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 460-462

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Elucidation of the reversible carbon monoxide reactions of a paramagnetic rhodium(II) complex

K. R. Dunbar, S. C. Haefner and P. N. Swepston, J. Chem. Soc., Chem. Commun., 1991, 460 DOI: 10.1039/C39910000460

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