Issue 1, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

The oxygenation of the electron-rich triple bond in the complexes [Re2X4(µ-dppm)2][X = Cl or Br; dppm = bis(diphenylphosphino)methane]. Multielectron redox behaviour involving retention of the Re2X4P4 unit

Stuart L. Bartley,   Kim R. Dunbar,   Keng-Yu Shih,   Phillip E. Fanwick  and  Richard A. Walton  

Abstract

The reactions of the triply bonded complexes [Re2X4(µ-dppm)2](X = Cl or Br; dppm = Ph2PCH2PPh2) with O2 proceed to give the products [Re2(µ-O)(µ-X)(O)X3(µ-dppm)2] and [Re2(µ-O)(O)2X4(dppm)2] in high yield in which net four- and six-electron redox reactions have occurred and the integrity of the ligand sets of the precursor complex is preserved.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39930000098
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 98-100

Permissions

Request permissions

The oxygenation of the electron-rich triple bond in the complexes [Re2X4(µ-dppm)2][X = Cl or Br; dppm = bis(diphenylphosphino)methane]. Multielectron redox behaviour involving retention of the Re2X4P4 unit

S. L. Bartley, K. R. Dunbar, K. Shih, P. E. Fanwick and R. A. Walton, J. Chem. Soc., Chem. Commun., 1993, 98 DOI: 10.1039/C39930000098

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements