Pressure-induced Jahn–Teller switching in a Mn12 nanomagnet

Pascal Parois; Stephen A. Moggach; Javier Sanchez-Benitez; Konstantin V. Kamenev; Alistair R. Lennie; John E. Warren; Euan K. Brechin; Simon Parsons; Mark Murrie

doi:10.1039/B923962F

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Pressure-induced Jahn–Teller switching in a Mn₁₂ nanomagnet†

Pascal Parois,^a Stephen A. Moggach,^b Javier Sanchez-Benitez,^b Konstantin V. Kamenev,^b Alistair R. Lennie,^c John E. Warren,^c Euan K. Brechin,^b Simon Parsons*^b and Mark Murrie*^a

Author affiliations

* Corresponding authors

^a WestCHEM, Department of Chemistry, University of Glasgow, University Avenue, Glasgow, UK
E-mail: M.Murrie@chem.gla.ac.uk
Fax: +44 (0)141 330 4888

^b School of Chemistry and Centre for Science at Extreme Conditions, University of Edinburgh, West Mains Road, Edinburgh, UK
E-mail: S.Parsons@ed.ac.uk

^c STFC Daresbury Laboratory, Warrington, Cheshire, UK

Abstract

Pressure-induced switching of a fast-relaxing single-molecule magnet to a slow-relaxing isomer is observed for the first time by using a combination of high pressure single-crystal X-ray diffraction and high pressure magnetic measurements.

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Article information

DOI: https://doi.org/10.1039/B923962F
Article type: Communication
Submitted: 16 Nov 2009
Accepted: 21 Dec 2009
First published: 18 Jan 2010

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Chem. Commun., 2010,46, 1881-1883

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Pressure-induced Jahn–Teller switching in a Mn₁₂ nanomagnet

P. Parois, S. A. Moggach, J. Sanchez-Benitez, K. V. Kamenev, A. R. Lennie, J. E. Warren, E. K. Brechin, S. Parsons and M. Murrie, Chem. Commun., 2010, 46, 1881 DOI: 10.1039/B923962F

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