Paper
Chem. Commun., 1999, 2181 - 2182, DOI: 10.1039/a906497d
Change of electron-transfer path-selectivity in a triad by F–-coordination at a boronate-ester bridge
Hideo Shiratori, Atsuhiro Osuka, Takeshi Ohno and Koichi Nozaki
In a triad comprising of a zinc porphyrin donor (ZP) appended to a naphthalene-1,8
4,5-tetracarboxylic diimide (NI) and a pyromellitic diimide (PI) through a boronate ester and an acetal bridge, respectively, F–-coordination at the boronate bridge induced clear switching of the electron-transfer path from 1ZP*
NI to 1ZP*
PI.
