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Chem. Commun., 2002, 636 - 637, DOI: 10.1039/b111295n

11 Complexes of 5-(4-[N-tert-butyl-N-aminoxyl]phenyl)pyrimidine with manganese(II) and copper(II) hexafluoroacetonylacetonate

Lora M. Field, Paul M. Lahti and Fernando Palacio

Mn(hfac)2 and Cu(hfac)2 form 11 complexes with 5-(4-[N-tert-butyl-N-aminoxyl]phenyl)pyrimidine that exhibit strong metal–nitroxide exchange; spin polarization models do not explain the antiferromagnetic exchange behavior between spin sites in these complexes.

Graphical abstract image for this article (ID: b111295n)