Issue 1, 2003
From the journal:

Chemical Communications

Novel gas-phase ion–molecule aromatic nucleophilic substitution in β-carbolines

Norberto P. Lopes,ab   Tatiana Fonseca,a   John P. G. Wilkins,c   James Stauntona  and  Paul J. Gates*a  

* Corresponding authors

a Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: pjg1002@cam.ac.uk
Fax: 01223 336362
Tel: 01223 336359

b Faculdade de Ciências Farmacêuticas de Ribeirão Preto, Universidade de São Paulo, Via do Café S/N, CEP 14.040-903, Ribeirão Preto-SP, Brazil

c Unilever Safety and Environmental Assurance Centre, Colworth House, Sharnbrook, Bedfordshire, UK

Abstract

We report a novel gas-phase ion–molecule aromatic-nucleophilic substitution reaction between β-carbolines and water vapour, that accounts for the observation of ions with higher masses than the precursor ion in the MS/MS spectra.

Graphical abstract: Novel gas-phase ion–molecule aromatic nucleophilic substitution in β-carbolines

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Article information

DOI
https://doi.org/10.1039/B210117C
Article type
Communication
Submitted
17 Oct 2002
Accepted
08 Nov 2002
First published
26 Nov 2002

Chem. Commun., 2003, 72-73

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Novel gas-phase ion–molecule aromatic nucleophilic substitution in β-carbolines

N. P. Lopes, T. Fonseca, J. P. G. Wilkins, J. Staunton and P. J. Gates, Chem. Commun., 2003, 72 DOI: 10.1039/B210117C

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