Issue 22, 2003
From the journal:

Chemical Communications

Pore size effects in the pyrolysis of 1,3-diphenylpropane confined in mesoporous silicas

Michelle K. Kidder,a   Phillip F. Britt,a   Zongtao Zhang,a   Sheng Daia  and  A. C. Buchanan, III*a  

* Corresponding authors

a Chemical Sciences Division, Oak Ridge National Laboratory, Bethel Valley Road, Oak Ridge, Tennessee, USA
E-mail: buchananac@ornl.gov

Abstract

A new method for derivatizing mesoporous silicas, SBA-15 and MCM-41, with a substituted phenol is described, and pore confinement and surface curvature are shown to impact the reaction rate and product selectivity for the pyrolysis of surface-immobilized 1,3-diphenylpropane.

Graphical abstract: Pore size effects in the pyrolysis of 1,3-diphenylpropane confined in mesoporous silicas

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Article information

DOI
https://doi.org/10.1039/B310405B
Article type
Communication
Submitted
27 Aug 2003
Accepted
23 Sep 2003
First published
15 Oct 2003

Chem. Commun., 2003, 2804-2805

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Pore size effects in the pyrolysis of 1,3-diphenylpropane confined in mesoporous silicas

M. K. Kidder, P. F. Britt, Z. Zhang, S. Dai and A. C. Buchanan, III, Chem. Commun., 2003, 2804 DOI: 10.1039/B310405B

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