Communication

Chem. Commun., 2004, 830 - 831, DOI: 10.1039/b311292f

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On the relative migratory aptitudes of carbon and heteroatoms in borate complexes. A surprising -thia effect

Jonathan M. Stoddard and Kenneth J. Shea

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Dimethylsulfoxonium methylide reacts with dicyclohexyl(-thiophenylmethyl)methylborane via 1,2-alkyl migration and alkyldithiaborolane via 1,2-sulfur migration.

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