Issue 22, 2004
From the journal:

Chemical Communications

Electrophilicity parameters for σ-complexation by uncharged electron-deficient aromatic and heteroaromatic structures

François Terrier,*a   Sami Lakhdar,ab   Régis Goumont,a   Taoufik Boubakerb  and  Erwin Buncelc  

* Corresponding authors

a Laboratoire SIRCOB, UMR 8086, Institut Lavoisier-Franklin, University of Versailles, 45, Avenue des Etats-Unis, Versailles Cedex, France

b Unité de Recherche de Physico-Chimie Moléculaire, Faculté des Sciences de Monastir, Avenue de l'Environnement, Monastir, Tunisie

c Department of Chemistry, Queen's University, Kingston, ON K7L 3N6, Canada
E-mail: terrier@chimie.uvsq.fr

Abstract

Using appropriate sets of reference nucleophiles, the reactivity of neutral electrophiles of widely different reactivity and structure has been ranked on the comprehensive electrophilicity scale of Mayr (Acc. Chem. Res., 2003, 36, 66), holding promise of a general rationalization of σ-complexation processes and related SNAr substitutions.

Graphical abstract: Electrophilicity parameters for σ-complexation by uncharged electron-deficient aromatic and heteroaromatic structures

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Article information

DOI
https://doi.org/10.1039/B410356D
Article type
Communication
Submitted
08 Jul 2004
Accepted
25 Aug 2004
First published
30 Sep 2004

Chem. Commun., 2004, 2586-2587

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Electrophilicity parameters for σ-complexation by uncharged electron-deficient aromatic and heteroaromatic structures

F. Terrier, S. Lakhdar, R. Goumont, T. Boubaker and E. Buncel, Chem. Commun., 2004, 2586 DOI: 10.1039/B410356D

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