Issue 19, 2005

The step-wise assembly of an undecanuclear heterotrimetallic cyanide cluster

Abstract

The step-wise assembly of the high nuclearity cluster, {[NiII(H2O)5]6[CoIII(tmphen)2]3[FeII(CN)6]2}13+, is achieved by treating {[Co(tmphen)2]3[Fe(CN)6]2} with six equivalents of Ni(ClO4)2 in aqueous MeOH.

Graphical abstract: The step-wise assembly of an undecanuclear heterotrimetallic cyanide cluster

Supplementary files

Article information

Article type
Communication
Submitted
14 Dec 2004
Accepted
09 Mar 2005
First published
12 Apr 2005

Chem. Commun., 2005, 2451-2453

The step-wise assembly of an undecanuclear heterotrimetallic cyanide cluster

C. P. Berlinguette and K. R. Dunbar, Chem. Commun., 2005, 2451 DOI: 10.1039/B418698B

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