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Chem. Commun., 2005, 2606 - 2608, DOI: 10.1039/b503173g


Hindered rotation in an exploded biphenyl

Ognjen . Miljani, Sangdon Han, Daniel Holmes, Gaston R. Schaller and K. Peter C. Vollhardt


The first cases of hindered rotation around the triple bond in simple diphenylacetylenes were observed, including that in chiral 2,2-bis(trimethylsilyl)-6,6-bis(dimethylthexylsilyl)diphenylacetylene.

Graphical abstract image for this article  (ID: b503173g)