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Communication
Chem. Commun., 2005, 4723 - 4725, DOI: 10.1039/b509188h
Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes
Xile Hu, Brandi M. Cossairt, Bruce S. Brunschwig, Nathan S. Lewis and Jonas C. Peters
In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as –0.28 V vs. SCE.
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