Issue 46, 2005

A novel sheet 4f–3d mixed-metal pyridine dicarboxylate: synthesis, structure, photophysical properties and its transformation to a perovskite oxide

Abstract

The synthesis, characterization and photophysical properties of a 4f–3d mixed metal compound, Gd(H2O)3Co[C5N1H3(COO)2]3, are described; the structure is unique, consisting of sheets with large pores (ca. 7 Å diameter) in the sheets and transforms to a perovskite oxide at moderate temperatures.

Graphical abstract: A novel sheet 4f–3d mixed-metal pyridine dicarboxylate: synthesis, structure, photophysical properties and its transformation to a perovskite oxide

Supplementary files

Article information

Article type
Communication
Submitted
07 Jul 2005
Accepted
22 Sep 2005
First published
20 Oct 2005

Chem. Commun., 2005, 5787-5789

A novel sheet 4f–3d mixed-metal pyridine dicarboxylate: synthesis, structure, photophysical properties and its transformation to a perovskite oxide

P. Mahata, G. Sankar, G. Madras and S. Natarajan, Chem. Commun., 2005, 5787 DOI: 10.1039/B509588C

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