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Communication
Chem. Commun., 2006, 520 - 522, DOI: 10.1039/b514280f
Iron hydrogenase active site mimic holding a proton and a hydride
Lennart Schwartz, Gerriet Eilers, Lars Eriksson, Adolf Gogoll, Reiner Lomoth and Sascha Ott
The first model of the iron hydrogenase active site has been prepared which concomitantly carries a proton and a hydride; the title species was characterized by IR and NMR spectroscopy and is reduced at more positive potential than any other mimic of this kind.
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