Issue 24, 2006

Migratory insertion of [B(C6F5)2] into C–H bonds: CO promoted transfer of the boryl fragment

Abstract

The reaction of (η5-C5H5)Fe(CO)2B(C6F5)2 with CO has been shown to proceed via ligand substitution at the metal with accompanying transfer of the boryl fragment (via C–H insertion) to the Cp ring, thereby generating the zwitterion [η5-C5H4B(C6F5)2H]Fe(CO)3 in quantitative yield.

Graphical abstract: Migratory insertion of [B(C6F5)2] into C–H bonds: CO promoted transfer of the boryl fragment

Supplementary files

Article information

Article type
Communication
Submitted
21 Mar 2006
Accepted
21 Apr 2006
First published
10 May 2006

Chem. Commun., 2006, 2578-2580

Migratory insertion of [B(C6F5)2] into C–H bonds: CO promoted transfer of the boryl fragment

S. Aldridge, D. L. Kays (née Coombs), A. Al-Fawaz, K. M. Jones, P. N. Horton, M. B. Hursthouse, R. W. Harrington and W. Clegg, Chem. Commun., 2006, 2578 DOI: 10.1039/B604141H

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