Issue 33, 2007
From the journal:

Chemical Communications

pH-Induced formation of metalloligand: increasing structure dimensionality by tuning number of ligand functional sites†

Wen-Xiu Ni,a   Mian Li,a   Xiao-Ping Zhou,a   Zhen Li,a   Xiao-Chun Huanga  and  Dan Li*a  

* Corresponding authors

a Department of Chemistry, Shantou University, Guangdong, P. R. China
E-mail: dli@stu.edu.cn
Fax: +86 754 290-2767
Tel: +86 754 290-2741

Abstract

Two complexes, 2D [Cu2(CN)2(4-Hpcih)]n and 3D {[Cu2(CN)1.5(4-pcih)]·1.25H2O}n (4-Hpcih = 4-pyridinecarbaldehyde isonicotinoyl hydrazone), were obtained using a synthetic approach of pH-induced formation of metalloligands, successfully demonstrating a strategy to increase structure dimensionality by tuning the number of ligand functional sites.

Graphical abstract: pH-Induced formation of metalloligand: increasing structure dimensionality by tuning number of ligand functional sites

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Article information

DOI
https://doi.org/10.1039/B705603F
Article type
Communication
Submitted
12 Apr 2007
Accepted
02 Jul 2007
First published
24 Jul 2007

Chem. Commun., 2007, 3479-3481

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pH-Induced formation of metalloligand: increasing structure dimensionality by tuning number of ligand functional sites

W. Ni, M. Li, X. Zhou, Z. Li, X. Huang and D. Li, Chem. Commun., 2007, 3479 DOI: 10.1039/B705603F

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