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Chem. Commun., 2007, 3482 - 3484, DOI: 10.1039/b705719a

Thermodynamically- and kinetically-controlled Friedel–Crafts alkenylation of arenes with alkynes using an acidic fluoroantimonate(V) ionic liquid as catalyst

Doo Seong Choi, Jin Hong Kim, Ueon Sang Shin, Ravindra R. Deshmukh and Choong Eui Song

By employing superacidic fluoroantimonate ionic liquid (IL), [bmim][Sb2F11], as catalyst, not only thermodynamically-controlled but also kinetically-controlled Friedel–Crafts alkenylations of arenes with alkynes have been realized for the first time.

Graphical abstract image for this article (ID: b705719a)