Issue 4, 2008
From the journal:

Chemical Communications

Photodimerization of a 1D hydrogen-bonded zwitter-ionic lead(ii) complex and its isomerization in solution†

Abdul Malik Puthan Peedikakkal,a   Lip L. Koha  and  Jagadese J. Vittal*a  

* Corresponding authors

a Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543
E-mail: chmjjv@nus.edu.sg
Fax: +65 6779 1691
Tel: +65 6516 2975

Abstract

A pair of bpe–H+ ligands in a zwitter-ionic complex undergoes photochemical cycloaddition quantitatively accompanied by proton transfer and the cyclobutane ring isomerizes slowly in solution to two more isomers, catalyzed by CF3CO2H acid.

Graphical abstract: Photodimerization of a 1D hydrogen-bonded zwitter-ionic lead(ii) complex and its isomerization in solution

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Article information

DOI
https://doi.org/10.1039/B714355A
Article type
Communication
Submitted
18 Sep 2007
Accepted
18 Oct 2007
First published
29 Oct 2007

Chem. Commun., 2008, 441-443

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Photodimerization of a 1D hydrogen-bonded zwitter-ionic lead(II) complex and its isomerization in solution

A. M. P. Peedikakkal, L. L. Koh and J. J. Vittal, Chem. Commun., 2008, 441 DOI: 10.1039/B714355A

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