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Chem. Commun., 2008, 3064 - 3066, DOI: 10.1039/b803043j

Copper-free click chemistry for the in situ crosslinking of photodegradable star polymers

Jeremiah A. Johnson, Jeremy M. Baskin, Carolyn R. Bertozzi, Jeffrey T. Koberstein and Nicholas J. Turro

Bifunctional, fluorinated cyclooctynes were used for the in situ click crosslinking of azide-terminated photodegradable star polymers, yielding photodegradable polymeric model networks with well-defined structures and tunable gelation times.

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