Issue 17, 2009
From the journal:

Chemical Communications

Diastereoselective self-assembly of dinuclear heterochiral metallosupramolecular rhombs in a self-discriminating process†

Torsten Weilandt,a   Ulf Kiehne,a   Gregor Schnakenburgb  and  Arne Lützen*a  

* Corresponding authors

a Rheinische Friedrich-Wilhelms Universität Bonn, Kekulé-Institut für Organische Chemie und Biochemie, Gerhard-Domagk-Str. 1, D-53121 Bonn, Germany
E-mail: arne.luetzen@uni-bonn.de
Fax: 0049228739608
Tel: 0049228737533

b Rheinische Friedrich-Wilhelms Universität Bonn, Institut für Anorganische Chemie, Gerhard-Domagk-Str. 1, D-53121 Bonn, Germany

Abstract

A racemic bis(nitrile) ligand based on the Tröger’s base scaffold self-assembles into an achiral dinuclear heterochiral rhomb in a diastereoselective self-discrimination process; this occurs upon coordination to (dppp)Pd(OTf)2 as evidenced by nmr spectroscopy and X-ray crystal structure analysis.

Graphical abstract: Diastereoselective self-assembly of dinuclear heterochiral metallosupramolecular rhombs in a self-discriminating process

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Article information

DOI
https://doi.org/10.1039/B819335E
Article type
Communication
Submitted
30 Oct 2008
Accepted
27 Feb 2009
First published
17 Mar 2009

Chem. Commun., 2009, 2320-2322

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Diastereoselective self-assembly of dinuclear heterochiral metallosupramolecular rhombs in a self-discriminating process

T. Weilandt, U. Kiehne, G. Schnakenburg and A. Lützen, Chem. Commun., 2009, 2320 DOI: 10.1039/B819335E

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