Issue 26, 2009

Synthesis and structural characterisation of stable cationic gold(i) alkene complexes

Abstract

Treatment of [AuCl(PBut3)] with AgSbF6 in CH2Cl2 at room temperature in the presence of the alkenes norbornene, norbornadiene, trans-cyclooctene, and also interestingly, isobutylene, leads to the formation of stable crystalline complexes [Au(PBut3)(alkene)][SbF6], characterised by NMR spectroscopy and X-ray crystallography.

Graphical abstract: Synthesis and structural characterisation of stable cationic gold(i) alkene complexes

Supplementary files

Article information

Article type
Communication
Submitted
22 Apr 2009
Accepted
19 May 2009
First published
05 Jun 2009

Chem. Commun., 2009, 3877-3879

Synthesis and structural characterisation of stable cationic gold(I) alkene complexes

T. N. Hooper, M. Green, J. E. McGrady, J. R. Patel and C. A. Russell, Chem. Commun., 2009, 3877 DOI: 10.1039/B908109G

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