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Chem. Commun., 2009, 7512 - 7514, DOI: 10.1039/b910378c


The commensurate modulated structure of the metastable state in spin crossover complex [Fe(abpt)2(NCS)2]

Chou-Fu Sheu, Szu-Miao Chen, Shih-Chi Wang, Gene-Hsiang Lee, Yi-Hung Liu and Yu Wang


Two new polymorphs (C and D) of [t-Fe(abpt)2(NCS)2] are characterized, a commensurate modulated structure with the c axis tripled in the thermally quenched metastable high spin state at 25 K is found in polymorph C.

Graphical abstract image for this article  (ID: b910378c)