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Article citation: Masamichi Ogasawara, Chem. Commun., 2009, DOI: 10.1039/b912531k

Synthesis of fluorinated allenes via palladium-catalyzed monofluoromethylation using FBSM

Masamichi Ogasawara, Hidetoshi Murakami, Tatsuya Furukawa, Tamotsu Takahashi and Norio Shibata

Palladium-catalyzed monofluoromethylation of substituted 2-bromo-1,3-dienes using fluorobis(phenylsulfonyl)methane (FBSM) as a pronucleophile gave previously unknown monofluoromethylated allenes in high yields, which are the isosteres of biologically attractive allenic alcohols.

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