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Chem. Commun., 2010, 46, 604 - 606, DOI: 10.1039/b914582f

Metal–organic replica of chiral natural material -SnF2: an enantiopure binodal (3,5)-connected net based on triangular and trigonal bipyramidal coordination

Jie Qin, Chao Qin, Xin-Long Wang, En-Bo Wang and Zhong-Min Su

A chiral (3,5)-connected metal–organic framework, based on triangular and trigonal bipyramidal coordiantion, exhibits an unprecedented -SnF2 topology, and represents the first heterocoordinated chiral metal–organic analogue presently known with a natural material topology.

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