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Chem. Commun., 2009, 7143 - 7145, DOI: 10.1039/b915083h

Splendid symmetry: crystallization of an unbridged isomer of Co2(CO)8 in Co2(CO)8·C60

Thelma Y. Garcia, James C. Fettinger, Marilyn M. Olmstead and Alan L. Balch

Cocrystallization of Co2(CO)8 with C60 traps the cobalt carbonyl molecule as the D3d isomer that otherwise is not available for crystallographic analysis.

Graphical abstract image for this article (ID: b915083h)