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Communication
Chem. Commun., 2009, 7566 - 7568, DOI: 10.1039/b917156h
Synthesis of transition metal isocyanide compounds from carbonyl complexes via reaction with Li[Me3SiNR]
Wesley Sattler and Gerard Parkin
The reaction between a transition metal carbonyl compound, LnMCO, and Li[Me3SiNR] yields the corresponding isocyanide derivative, LnMCNR, thereby providing a new route to transition metal isocyanide compounds that does not require the use of free isocyanides as reagents.
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