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Chem. Commun., 2010, 46, 85 - 87, DOI: 10.1039/b920090h

Single and double substrate insertion into the TiN bonds of terminal titanium hydrazides

Pei-Jen Tiong, A. Daniel Schofield, Jonathan D. Selby, Ainara Nova, Eric Clot and Philip Mountford

Nitriles, CO2 and isocyanates undergo net single or double insertion reactions into the TiN multiple bonds of terminal titanium hydrazides. These are the first such examples of this type of reactivity for any transition metal hydrazide complex.

Graphical abstract image for this article (ID: b920090h)