Issue 10, 2010
From the journal:

Chemical Communications

Dehydrogenation of amine–boranes with a frustrated Lewis pair†

Alexander J. M. Miller*a  and  John E. Bercawa  

* Corresponding authors

a Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, CA, USA
E-mail: ajmiller@caltech.edu
Fax: +1 626 585 0147
Tel: +1 626 395 6576

Abstract

Bulky tertiary phosphine/borane Lewis pairs PtBu3/B(C6F5)3 react with amine–boranes to afford dehydrocoupling products and phosphonium borohydride salts.

Graphical abstract: Dehydrogenation of amine–boranes with a frustrated Lewis pair

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Article information

DOI
https://doi.org/10.1039/B925659H
Article type
Communication
Submitted
07 Dec 2009
Accepted
16 Jan 2010
First published
02 Feb 2010

Chem. Commun., 2010,46, 1709-1711

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Dehydrogenation of amine–boranes with a frustrated Lewis pair

A. J. M. Miller and J. E. Bercaw, Chem. Commun., 2010, 46, 1709 DOI: 10.1039/B925659H

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