RSC Publishing


Publishing

 

Cover image for Physical Chemistry Chemical Physics, select for current issue

Physical Chemistry Chemical Physics

High quality research in physical chemistry, chemical physics and biophysical chemistry.



Subscribers

Non-subscribers

Free access



Paper

Phys. Chem. Chem. Phys., 2009, 11, 9653 - 9666, DOI: 10.1039/b911179d


Generalization of the continuous symmetry measure: the symmetry of vectors, matrices, operators and functions

Chaim Dryzun and David Avnir


In this paper we generalize a method for evaluating the continuous symmetry measure, which is a quantitative estimate of the degree of symmetry of a given object. The generalization makes it possible to calculate the degree of symmetry content for any mathematical entity that is part of metric spaces such as vectors, matrices, operators and functions. Furthermore, by this new approach one can calculate the symmetry-content values for any compact symmetry groups either finite or infinite. An advantage of the new methodology is the ability to investigate analytically problems of symmetry changes. Examples of symmetry evaluation calculations are provided, including mixing of ideal gases, evaluation of the symmetry content of a Hamiltonian operator, the 2pz orbital of the hydrogen atom, and more.

Graphical abstract image for this article  (ID: b911179d)