Tutorial Review

Chem. Soc. Rev., 2010, 39, 61 - 69, DOI: 10.1039/b907303p

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Development and applications of tethered bis(8-quinolinolato) metal complexes (TBOxM)

Joshua P. Abell and Hisashi Yamamoto

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The tethered bis(8-quinolinolato) metal (TBOxM) complexes have found practical use in many asymmetric reactions. The development of highly enantioselective reactions using TBOxM is surveyed. General reaction schemes and examples using these highly active and selective catalysts are given and discussed in this tutorial review.

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