Issue 14, 1976
From the journal:

Journal of the Chemical Society, Dalton Transactions

Studies of phosphazenes. Part I. Reactions of octachlorocyclotetraphosphazatetraene with ethylamine

S. S. Krishnamurthy,   Arjun Chandra Sau,   A. R. Vasudeva Murthy,   Rodney Keat,   Robert A. Shaw  and  Michael Woods  

Abstract

The reaction of octachlorocyclotetraphosphazatetraene, N4P4Cl8, with ethylamine has been investigated. Seven derivatives, N4P4Cl8–n(NHEt)n[n= 1, 2 (two isomers), 3, 4 (two isomers), and 8] have been isolated and their structures established by 1H and 31P n.m.r. spectroscopy. A non-geminal chlorine atom replacement scheme is observed. Attempts to prepare penta- or hexa-ethylamino derivatives were unsuccessful: only sticky, non-crystalline resins were obtained from 1 : 10 or 1 : 12 reactions. The preparation and n.m.r. spectroscopic data of mixed ethylamino(methoxy)-derivatives. N4P4(NHEt)–8-n(OMe)n[n= 6, 4 (two isomers)], and an ethylamino-(dimethylamino)-derivative, N4P4(NHEt)2(NMe2)6, are generally consistent with the proposed structures. The reaction pattern is discussed.

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Article information

DOI
https://doi.org/10.1039/DT9760001405
Article type
Paper

J. Chem. Soc., Dalton Trans., 1976, 1405-1410

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Studies of phosphazenes. Part I. Reactions of octachlorocyclotetraphosphazatetraene with ethylamine

S. S. Krishnamurthy, A. C. Sau, A. R. V. Murthy, R. Keat, R. A. Shaw and M. Woods, J. Chem. Soc., Dalton Trans., 1976, 1405 DOI: 10.1039/DT9760001405

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