Issue 3, 2004

The first example of a Si-bridged tris(pyridyl) ligand; synthesis and structure of [MeSi(2-C5H4N)3LiX] (X = 0.2Br, 0.8Cl)

Abstract

The low-temperature reaction of MeSiCl3 with 2-Li–C5H4N (1 ∶ 3 equivalents) in thf gives [MeSi(2-C5H4N)3LiX] (X = 0.2Br, 0.8Cl), containing the first example of a Si-bridged tris(pyridyl) ligand.

Graphical abstract: The first example of a Si-bridged tris(pyridyl) ligand; synthesis and structure of [MeSi(2-C5H4N)3LiX] (X = 0.2Br, 0.8Cl)

Supplementary files

Article information

Article type
Communication
Submitted
01 Dec 2003
Accepted
18 Dec 2003
First published
08 Jan 2004

Dalton Trans., 2004, 361-362

The first example of a Si-bridged tris(pyridyl) ligand; synthesis and structure of [MeSi(2-C5H4N)3LiX] (X = 0.2Br, 0.8Cl)

F. García, A. D. Hopkins, S. M. Humphrey, M. McPartlin, M. C. Rogers and D. S. Wright, Dalton Trans., 2004, 361 DOI: 10.1039/B315503J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements