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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry




Communication

Dalton Trans., 2008, 4392 - 4394, DOI: 10.1039/b803304h


Can the hexamethylhydrazinium dication [Me3N–NMe3]2+ be prepared?

Yun Zhang and Christopher A. Reed


The long sought hexamethylhydrazinium(2+) dication, Me3N–NMe32+, calculationally unstable towards coulombic explosion because of formal positive charges on adjacent N atoms, can be synthesized and isolated as a CHB11Cl11- carborane salt.

Graphical abstract image for this article  (ID: b803304h)