Issue 38, 2009
From the journal:

Dalton Transactions

Synthesis of a one-dimensional coordination polymer containing pendant hydrosulfidegroups†

Jyotsna Chaturvedi,a   Subrato Bhattacharya*a  and  M. Nethajib  

* Corresponding authors

a Department of Chemistry, Banaras Hindu University, Varanasi, India
E-mail: s_bhatt@bhu.ac.in

b Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore, India

Abstract

In view of the recent interest in compounds containing M–SH units, an organotin hydrosulfide compound, Me2Sn(SH)(O2CMe) (1) was prepared by controlled hydrolysis of the diorganotin thioacetate. Under similar mild hydrolytic conditions the corresponding benzoate could not be isolated. Instead, the thiobenzoate complex, Me2Sn(SOCPh)2 (3) was obtained in excellent yields indicating that there was no hydrolysis. Both 1 and 3 were characterized by X-ray crystallography. Some properties of the polymeric compound 1, such as spectral, electrical conductivity and NLO response were also studied. The reactivity and properties were explained using density functional calculations.

Graphical abstract: Synthesis of a one-dimensional coordination polymer containing pendant hydrosulfide groups

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Article information

DOI
https://doi.org/10.1039/B908304A
Article type
Paper
Submitted
19 May 2009
Accepted
11 Aug 2009
First published
24 Aug 2009

Dalton Trans., 2009, 8018-8024

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Synthesis of a one-dimensional coordination polymer containing pendant hydrosulfide groups

J. Chaturvedi, S. Bhattacharya and M. Nethaji, Dalton Trans., 2009, 8018 DOI: 10.1039/B908304A

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