Self-assembly of a PdII neutral molecular rectangle via a new organometallic PdII2 molecular clip and oxygen donor linker

Arun Kumar Bar; Bappaditya Gole; Sushobhan Ghosh; Partha Sarathi Mukherjee

doi:10.1039/B911622M

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Self-assembly of a Pd^II neutral molecular rectangle via a new organometallic Pd^II₂ molecular clip and oxygen donor linker†

Arun Kumar Bar,^a Bappaditya Gole,^a Sushobhan Ghosh^a and Partha Sarathi Mukherjee*^a

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^a Inorganic and Physical Chemistry Department, Indian Institute of Science, India
E-mail: psm@ipc.iisc.ernet.in
Fax: +91-80-2360-1552
Tel: +91-80-2293-3352

Abstract

Two components self-assembly of a Pd₄ neutral molecular rectangle driven by Pd–O bond coordination has been achieved and this π-electron rich rectangle shows fluorescence quenching in presence of nitroaromatics, which are the chemical signatures of many explosives.

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Article information

DOI: https://doi.org/10.1039/B911622M
Article type: Communication
Submitted: 12 Jun 2009
Accepted: 19 Jun 2009
First published: 24 Jun 2009

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Dalton Trans., 2009, 6701-6704

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Self-assembly of a Pd^II neutral molecular rectangle via a new organometallic Pd^II₂ molecular clip and oxygen donor linker

A. K. Bar, B. Gole, S. Ghosh and P. S. Mukherjee, Dalton Trans., 2009, 6701 DOI: 10.1039/B911622M

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Dalton Transactions