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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry




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Dalton Trans., 2010, 39, 1191 - 1194, DOI: 10.1039/b915953c


A double-stranded dinuclear cadmium(II) helicate that assembles into chains in the solid state

Miguel Martínez-Calvo, Ana M. González-Noya, Rosa Pedrido, María J. Romero, M. Isabel Fernández, Guillermo Zaragoza and Manuel R. Bermejo


A [4+4] double-stranded cadmium dihelicate was afforded from an easily accessible thiosemicarbazone ligand; its crystal structure reveals the assembly of two enantiomers into dihelicate pairs, these pairs being further connected into infinite linear chains.

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