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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry



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Dalton Trans., 2010, 39, 56 - 58, DOI: 10.1039/b919048a

3D MnII coordination polymer with alternating azide/azide/formate/formate bridged chains: synthesis, structure and magnetic properties

Jiong-Peng Zhao, Bo-Wen Hu, Qian Yang, Xiao-Feng Zhang, Tong-Liang Hu and Xian-He Bu

A new 3D MnII coordination polymer, [Mn2(HCO2)( L)2(N3)·MeOH] ( 1) ( L = nicotinate N-oxide), was synthesized by a solvothermal reaction and characterized magnetically. Complex 1 is a typical antiferromagnet with alternating azide/azide/formate/formate bridges, exhibiting a new –J1J1J2J2– coupling sequence. This is the first complex to contain an azide, formate and another type of carboxylate ligand.

Graphical abstract image for this article (ID: b919048a)