Issue 4, 1996

Solvothermal synthesis and structural characterisation of the first ammonium cobalt gallium phosphate hydrate, NH4[CoGa2P3O12(H2O)2]

Abstract

The first ammonium cobalt gallium phosphate hydrate, NH4[CoGa2P3O12(H2O)2] has been prepared under solvothermal conditions and the structure determined using single-crystal X-ray diffraction [space group C2/c, a= 13.323(3), b= 10.245(1), c= 8.886(2)Å, β= 108.43(2)°, V= 1150.68 Å3, Z= 4]. The structure consists of GaO5, CoO6 and PO4 polyhedra linked to form a microporous three-dimensional framework containing channels in which the NH4+ cations reside.

Article information

Article type
Paper

J. Mater. Chem., 1996,6, 611-614

Solvothermal synthesis and structural characterisation of the first ammonium cobalt gallium phosphate hydrate, NH4[CoGa2P3O12(H2O)2]

A. M. Chippindale, A. R. Cowley and R. I. Walton, J. Mater. Chem., 1996, 6, 611 DOI: 10.1039/JM9960600611

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