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Organic & Biomolecular Chemistry

The international home of synthetic, physical and biomolecular organic chemistry.




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Org. Biomol. Chem., 2005, 3, 2914 - 2916, DOI: 10.1039/b508820h


Titanocene(II)-promoted carbonyl allenation utilizing 1,1-dichloroalk-1-enes

Tomohiro Shono, Kenji Ito, Akira Tsubouchi and Takeshi Takeda


Treatment of 1,1-dichloroalk-1-enes with Cp2Ti[P(OEt)3]2 produced organotitanium species, which afford allenes on treatment with aldehydes and ketones.

Graphical abstract image for this article  (ID: b508820h)