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Organic & Biomolecular Chemistry

The international home of synthetic, physical and biomolecular organic chemistry.




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Org. Biomol. Chem., 2006, 4, 1202 - 1205, DOI: 10.1039/b600220j


Thiocarbonyl compounds as regulating reagent in the radical addition of tertiary amines with alkenes using photoelectron transfer conditions

Dominique Harakat, Jens Pesch, Sinia Marinkovi and Norbert Hoffmann


The efficiency of the photoinduced radical addition of tertiary amines to olefinic double bonds is significantly enhanced and the stereoselectivity is influenced when thiocarbonyl compounds are added to the reaction mixture.

Graphical abstract image for this article  (ID: b600220j)