Issue 16, 2008
From the journal:

Organic & Biomolecular Chemistry

Concise synthesis of bicyclic aminals and their evaluation as precursors to the sarain core

Anne J. Price Mortimer,a   Pui Shan Pang,a   Abil E. Aliev,a   Derek A. Tochera  and  Michael J. Porter*a  

* Corresponding authors

a Department of Chemistry, University College London, Christopher Ingold Building, 20 Gordon Street, London, UK
E-mail: m.j.porter@ucl.ac.uk
Fax: +44 20 7679 7463
Tel: +44 20 7679 4710

Abstract

A number of bicyclic aminals have been prepared in a stereospecific manner as potential precursors to the core structure of the sarain alkaloids. Rearrangement of these aminals to new diazabicyclic and diazatricyclic systems has been observed under various conditions.

Graphical abstract: Concise synthesis of bicyclic aminals and their evaluation as precursors to the sarain core

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Article information

DOI
https://doi.org/10.1039/B806031B
Article type
Paper
Submitted
10 Apr 2008
Accepted
16 May 2008
First published
19 Jun 2008

Org. Biomol. Chem., 2008,6, 2941-2951

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Concise synthesis of bicyclic aminals and their evaluation as precursors to the sarain core

A. J. Price Mortimer, P. S. Pang, A. E. Aliev, D. A. Tocher and M. J. Porter, Org. Biomol. Chem., 2008, 6, 2941 DOI: 10.1039/B806031B

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