Issue 11, 2009

Radical pairs with rotational fluidity in the photochemical reaction of acetophenone and cyclohexane in the zeolite NAY: a 13C CPMAS NMR and product analysis study

Abstract

The photochemical reaction of acetophenone and cyclohexane in the zeolite NaY occurs by combination of the geminate radical pairs to give products that reveal a significant amount of rotational fluidity, which was also documented by intermolecular nuclear dipolar interaction measurements using cross polarization 13C NMR (CPMAS) experiments.

Graphical abstract: Radical pairs with rotational fluidity in the photochemical reaction of acetophenone and cyclohexane in the zeolite NAY: a 13C CPMAS NMR and product analysis study

Article information

Article type
Paper
Submitted
02 Sep 2008
Accepted
17 Feb 2009
First published
16 Apr 2009

Org. Biomol. Chem., 2009,7, 2322-2326

Radical pairs with rotational fluidity in the photochemical reaction of acetophenone and cyclohexane in the zeolite NAY: a 13C CPMAS NMR and product analysis study

A. Amboya, T. Nguyen, H. T. Huynh, A. Brown, G. Ratliff, H. Yonutas, D. Cizmeciyan, A. Natarajan and M. A. Garcia Garibay, Org. Biomol. Chem., 2009, 7, 2322 DOI: 10.1039/B815266G

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