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Perkin Transactions 1 ceased publication in 2002. Organic & Biomolecular Chemistry is the RSC's journal for high-quality, original organic chemistry research.
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Paper
J. Chem. Soc., Perkin Trans. 1, 1995, 2203 - 2222, DOI: 10.1039/P19950002203
Enzymatic esterification and de-esterification of carbohydrates: synthesis of a naturally occurring rhamnopyranoside of p-hydroxybenzaldehyde and a systematic investigation of lipase-catalysed acylation of selected arylpyranosides
Nazir B. Bashir, Sara J. Phythian, Andrew J. Reason and Stanley M. Roberts
The regiocontrolled esterification and de-esterification of mono- and di-saccharides is reviewed. New results involving the enzyme-catalysed regioselective acylation of ribo-110, arabino-112, 119, xylo-111, and rhamnopyranosides 116, 118(as well as two arylpyranosides 125 and 136), are reported. This methodology is then applied to the total synthesis of the naturally occurring rhamnopyranoside 4-(4-O-acetyl-
-L-rhamnosyloxy)benzaldehyde 122.
