Issue 23, 1999

A short and efficient regioselective approach to the C-6 to C-19 segment of bifurcaranes and a formal total synthesis of β-microbiotene, microbiotol and cyclocuparanol

Abstract

Employing an epoxide rearrangement based ring contraction reaction, a short and efficient regioselective approach to the C-6 to C-19 segment of the toluquinol substituted diterpenes bifurcaranes, and its extension to a formal total synthesis of the sesquiterpenes (±)-β-microbiotene, (±)-microbiotol and (±)-cyclocuparanol are described.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1999, 3393-3394

A short and efficient regioselective approach to the C-6 to C-19 segment of bifurcaranes and a formal total synthesis of β-microbiotene, microbiotol and cyclocuparanol

A. Srikrishna and S. Anitha Nagamani, J. Chem. Soc., Perkin Trans. 1, 1999, 3393 DOI: 10.1039/A908033C

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