Issue 18, 1995
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Chiral crown ethers incorporating D-glucose

Puthuparampil P. Kanakamma,   Neelakandha S. Mani,   Uday Maitra  and  Vijay Nair  

Abstract

A novel class of crown ether derivatives incorporating D-glucose and poly(ethylene glycol) units has been synthesized from allyl α-D-glucopyranoside by a simple and efficient strategy. The complexing properties of these compounds with alkali metal cations and ammonium ion have been evaluated by Cram's picrate method. Catalytic activity of macrocycle 2 in asymmetric Michael addition reaction was also studied. The average cavity size of these macrocycles was determined by the application of the MMX programme.

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Article information

DOI
https://doi.org/10.1039/P19950002339
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1995, 2339-2344

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Chiral crown ethers incorporating D-glucose

P. P. Kanakamma, N. S. Mani, U. Maitra and V. Nair, J. Chem. Soc., Perkin Trans. 1, 1995, 2339 DOI: 10.1039/P19950002339

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