SCHEDULED MAINTENANCE
Short, stereoselective syntheses of dicyclopenta[a,d]cyclo-octane-based diones (14) and (+)-(22)via a 5-5-5-5→5-8-5 strategy are reported; our approach constitutes an effective methodology for constructing fusicoccane and ophiobolane-type natural products.
G. Mehta and N. Krishnamurthy, J. Chem. Soc., Chem. Commun., 1986, 1319 DOI: 10.1039/C39860001319
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