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Faraday Discuss. Chem. Soc., 1978, 66, 184 - 190, DOI: 10.1039/DC9786600184
Effects of liquid structures on chemical reactions and conformational changes of non-rigid molecules in condensed phases
David Chandler
A physical derivation of the rigorous theory for chemical equilibria and intramolecular structures of non-rigid molecules in condensed phases is presented. Applications of the theory are reviewed and the importance of steric or packing effects on equilibrium chemical phenomena in liquids is stressed.
